Nitroguanidine

Nitroguanidine
Names
IUPAC name
1-Nitroguanidine
Other names
Picrite
Identifiers
3D model (JSmol)
03, 126
ChEBI
ChemSpider
ECHA InfoCard 100.008.313
RTECS number
  • MF4600000
UNII
  • InChI=1S/CH4N4O2/c2-1(3)4-5(6)7/h(H4,2,3,4) Y
    Key: IDCPFAYURAQKDZ-UHFFFAOYSA-N Y
  • InChI=1/CH4N4O2/c2-1(3)4-5(6)7/h(H4,2,3,4)
    Key: IDCPFAYURAQKDZ-UHFFFAOYAN
  • NC(N)=N[N+]([O-])=O
Properties
(NH2)2CNNO2
Molar mass 104.069 g·mol−1
Appearance Colorless crystalline solid
Density 1.77 g/cm3
Melting point 239 °C (462 °F; 512 K) decomposes
  • 0.12 g/100mL (0 °C (32 °F; 273 K))
  • 0.42 g/100mL (25 °C (77 °F; 298 K))
  • 8.25 g/100mL (100 °C (212 °F; 373 K))
Solubility in Sulfuric acid 10.9 g/100mL (45% H2SO4)
Acidity (pKa) 12.2 (in 1 M NaCl at 24 °C (75 °F; 297 K))
Basicity (pKb) 15
Explosive data
Shock sensitivity
  • 4.4 lb (2 kg) weight, 19 in (47 cm) (Bureau of Mines apparatus)
  • 1 lb (0.45 kg) weight, 26 in (66 cm) (Picatinny Arsenal apparatus)
  • Unaffected - Rifle bullet impact.
Friction sensitivity Insensitive
Detonation velocity
  • 5,360 m/s (17,600 ft/s) (at specific gravity (sp. gr.) 1)
  • 7,650 m/s (25,100 ft/s) (at sp. gr. 1.5)
RE factor 1.01 (Trauzl test)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive when dry.
GHS labelling:(Stabilized with 25% water)
Danger
H228
P210, P240, P241, P280, P370+P378
NFPA 704 (fire diamond)
2
0
4
7 mg/m3 (TWA)
Lethal dose or concentration (LD, LC):
10200 mg/kg (oral, rat)
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Nitroguanidine - sometimes abbreviated NQ or NGu - is a colorless, crystalline solid that decomposes at 239 °C (462 °F), without melting. Nitroguanidine is an extremely insensitive but powerful high explosive. Nitroguanidine is used as an energetic material (propellant or high explosive), precursor for insecticides, and for other purposes.