Glycerol-1,2-carbonate

Glycerol-1,2-carbonate
Names
Other names
  • 4-Hydroxymethyl-1,3-dioxolan-2-one
  • 4-Hydroxymethyl-2-oxo-1,3-dioxolan
  • Glycerol carbonate
  • Hydroxypropylene carbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.012.032
EC Number
  • 213-235-0
UNII
  • InChI=1S/C4H6O4/c5-1-3-2-7-4(6)8-3/h3,5H,1-2H2
    Key: JFMGYULNQJPJCY-UHFFFAOYSA-N
  • C1C(OC(=O)O1)CO
Properties
C4H6O4
Molar mass 118.088 g·mol−1
Appearance clear, colourless to light yellow liquid
Density 1.40 g·cm−3 at 25 °C

1.41 g·cm−3 at 20 °C

Melting point −60 °C at 1013 hPa

−69 °C

Boiling point 110–115 °C at 0.1 mmHg

137–140 °C at 0.7 hPa
160 °C at 0.11 kPa
239 °C at 102.1 kPa

Miscible
Solubility Miscible in polar solvents such as alcohols

Miscible with tetrahydrofuran

Vapor pressure 0.93 Pa at 25 °C
1,4570 – 1,4610 (20 °C)

1,469 (20 °C)

Hazards
NFPA 704 (fire diamond)
2
1
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Glycerol-1,2-carbonate is formally the cyclic ester of carbonic acid with glycerol and has aroused great interest as a possible product from the "waste materials" carbon dioxide CO2 and glycerol (especially from biodiesel production) with a wide range of applications.

The currently unsatisfactory yields and complex process conditions in direct synthesis stand in the way of a further spread of glycerol carbonate as a solvent and molecular building block from renewable raw materials.