Carbonic acid

Carbonic acid
Names
IUPAC name
Carbonic acid
Other names
  • Oxidocarboxylic acid
  • Hydroxyformic acid
  • Hydroxymethanoic acid
  • Carbonylic acid
  • Hydroxycarboxylic acid
  • Dihydroxycarbonyl
  • Carbon dioxide solution
  • Aerial acid
  • Metacarbonic acid
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.133.015
EC Number
  • 610-295-3
25554
KEGG
UNII
  • InChI=1S/CH2O3/c2-1(3)4/h(H2,2,3,4) Y
    Key: BVKZGUZCCUSVTD-UHFFFAOYSA-N Y
  • InChI=1/H2O3/c2-1(3)4/h(H2,2,3,4)
    Key: BVKZGUZCCUSVTD-UHFFFAOYAU
  • O=C(O)O
Properties
H
2
CO
3
Appearance Colorless gas
Melting point −53 °C (−63 °F; 220 K) (sublimes)
Boiling point 127 °C (261 °F; 400 K) (decomposes)
Reacts to form carbon dioxide and water
Acidity (pKa)
  • pKa1 = 3.75 (25 °C; anhydrous)
  • pKa1 = 6.35 (hydrous)
  • pKa2 = 10.33
Conjugate base Bicarbonate, carbonate
Hazards
NFPA 704 (fire diamond)
0
0
1
Structure
monoclinic
p21/c, No. 14
-
a = 5.392 Å, b = 6.661 Å, c = 5.690 Å
α = 90°, β = 92.66°, γ = 90°
(D
2
CO
3
at 1.85 GPa, 298 K)
204.12 Å3
4 formula per cell
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Carbonic acid is a chemical compound with the chemical formula H2CO3. The molecule rapidly converts to water and carbon dioxide in the presence of water. In contrast to early-twentieth century textbooks, numerous studies conducted since ca. 1990 identified H2CO3 as a real molecule with a distinct Raman spectrum and with a first-order life-time of ca. 20 ms at 37 °C. Solid anhydrous carbonic acid has also been isolated.

The interconversion of carbon dioxide and carbonic acid is related to the breathing process of all aerobic organisms and to the acidification of natural waters.