Tulipalin A

Tulipalin A
Names
IUPAC name
α-methylene-γ-butyrolactone
Preferred IUPAC name
3-Methylideneoxolan-2-one
Other names
  • TUPA
Identifiers
3D model (JSmol)
107939
ChEBI
ChemSpider
ECHA InfoCard 100.008.120
EC Number
  • 208-931-6
746139
UNII
  • InChI=1S/C5H6O2/c1-4-2-3-7-5(4)6/h1-3H2
    Key: GSLDEZOOOSBFGP-UHFFFAOYSA-N
  • C=C1CCOC1=O
Properties
C5H6O2
Molar mass 98.101 g·mol−1
Density 1.085 g/ml
Melting point 25 °C (77 °F; 298 K)
Boiling point 168 °C (334 °F; 441 K)
Soluble in organic solvents like acetone and slightly soluble in water
Hazards
GHS labelling:
Warning
H226, H317
P210, P233, P240, P241, P242, P243, P261, P272, P280, P302+P352, P303+P361+P353, P321, P333+P313, P363, P370+P378, P403+P235, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tulipalin A, also known as α-methylene-γ-butyrolactone, is a naturally occurring compound found in certain flowers such as tulips and alstroemerias. Tulipalin A has the molecular formula C5H6O2 and the CAS registry number 547-65-9. It is an allergen and has been known to cause occupational contact dermatitis, i.e. 'tulip fingers,' in some who are commonly exposed to it such as florists. It has been shown to be synthesized from tuliposide A in response to damage to the plant. When the plant is damaged, tuliposide A is broken down by tuliposide-converting enzymes (TCE) to produce tulipalin A. More recent experiments with this compound have uncovered potential applications for it in the field of polymerization.