Trimethylsilyl acetate

Trimethylsilyl acetate
Names
IUPAC name
Trimethylsilyl acetate
Other names
  • Acetic acid trimethylsilyl ester
  • Acetoxytrimethylsilane
  • TMSOAc
Identifiers
3D model (JSmol)
EC Number
  • 220-404-2
UNII
  • InChI=1S/C5H12O2Si/c1-5(6)7-8(2,3)4/h1-4H3
    Key: QHUNJMXHQHHWQP-UHFFFAOYSA-N
  • CC(=O)O[Si](C)(C)C
Properties
CH3COOSi(CH3)3
Molar mass 132.234 g·mol−1
Appearance Colorless liquid
Odor Mild, sweet
Density 0.882 g/cm3, relative vapor density 4.57 (air = 1)
Melting point −32 °C (−26 °F; 241 K)
Boiling point 107.5 °C (225.5 °F; 380.6 K)
Soluble, reacts
Solubility Soluble in diethyl ether and ethanol
Vapor pressure 47 hPa at 30 °C
1.388
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly flammable
GHS labelling:
Danger
H225, H315, H319
P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P403+P235, P501
Flash point 19 °C (66 °F; 292 K)
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Trimethylsilyl acetate, also known as TMSOAc, is an organosilicon compound with the chemical formula CH3COOSi(CH3)3. It is a colorless liquid. It is the silyl ester analog of tert-butyl acetate, having a trimethylsilyl group −Si(CH3)3 in place of the tert-butyl group −C(CH3)3.