Thorium(IV) nitrate

Thorium(IV) nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.090
EC Number
  • (anhydrous): 237-514-1
UNII
  • (anhydrous): InChI=1S/4NO3.Th/c4*2-1(3)4;/q4*-1;+4
    Key: VGBPIHVLVSGJGR-UHFFFAOYSA-N
  • (tetrahydrate): InChI=1S/4NO3.4H2O.Th/c4*2-1(3)4;;;;;/h;;;;4*1H2;/q4*-1;;;;;+4
    Key: VAVIMIAZQDNXID-UHFFFAOYSA-N
  • (pentahydrate): InChI=1S/4NO3.5H2O.Th/c4*2-1(3)4;;;;;;/h;;;;5*1H2;/q4*-1;;;;;;+4
    Key: JFVMRMIHIHCMDY-UHFFFAOYSA-N
  • (hexahydrate): InChI=1S/4NO3.6H2O.Th/c4*2-1(3)4;;;;;;;/h;;;;6*1H2;/q4*-1;;;;;;;+4
    Key: HLGOSPFVTORIQZ-UHFFFAOYSA-N
  • (anhydrous): [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Th+4]
  • (tetrahydrate): [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.[Th+4]
  • (pentahydrate): [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.[Th+4]
  • (hexahydrate): [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Th+4]
Properties
Th(NO3)4
Molar mass
  • 480.066 (anhydrous)
  • 552.130 (tetrahydrate)
  • 570.146 (pentahydrate)
Appearance Colorless crystal
Density 2.8 g/cm3
Melting point 55 °C (131 °F; 328 K)
Boiling point Decomposes
4.013 mol/L at (25 °C (77 °F; 298 K))
Solubility alcohols, ketones, esters and ethers
Vapor pressure
  • 0.7 torrs (93 Pa) (25 °C (77 °F; 298 K))
  • 1.2 torrs (160 Pa) (42 °C (108 °F; 315 K))
  • 10.7 torrs (1.43 kPa) (68 °C (154 °F; 341 K))
Structure
orthorhombic
a = 1.1191 nm, b = 2.2889 nm, c = 1.0579 nm
(pentahydrate)
Thermochemistry
480.83 J/(K·mol)
−2.29 kJ/(K·mol)
Hazards
GHS labelling:
Warning
H272, H302, H315, H319, H335, H373, H411
P210, P220, P221, P260, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P314, P321, P330, P332+P313, P337+P313, P362, P370+P378, P391, P403+P233, P405, P501
Preview warning: Omit Rules: keep P260, omit P261
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.