Silver carbonate

Silver carbonate
Names
IUPAC name
Silver(I) carbonate
Other names
Argentous carbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.811
EC Number
  • 208-590-3
MeSH silver+carbonate
UNII
  • InChI=1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Y
    Key: KQTXIZHBFFWWFW-UHFFFAOYSA-L Y
  • InChI=1/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
    Key: KQTXIZHBFFWWFW-NUQVWONBAD
  • [Ag]OC(=O)O[Ag]
Properties
Ag2CO3
Molar mass 275.75 g/mol
Appearance Pale yellow crystals
Odor Odorless
Density 6.077 g/cm3
Melting point 218 °C (424 °F; 491 K)
decomposes from 120 °C
0.031 g/L (15 °C)
0.032 g/L (25 °C)
0.5 g/L (100 °C)
8.46·10−12
Solubility Insoluble in ethanol, liquid ammonia, acetates, acetone
−80.9·10−6 cm3/mol
Structure
Monoclinic, mP12 (295 K)
Trigonal, hP36 (β-form, 453 K)
Hexagonal, hP18 (α-form, 476 K)
P21/m, No. 11 (295 K)
P31c, No. 159 (β-form, 453 K)
P62m, No. 189 (α-form, 476 K)
2/m (295 K)
3m (β-form, 453 K)
6m2 (α-form, 476 K)
a = 4.8521(2) Å, b = 9.5489(4) Å, c = 3.2536(1) Å (295 K)
α = 90°, β = 91.9713(3)°, γ = 90°
Thermochemistry
112.3 J/mol·K
167.4 J/mol·K
−505.8 kJ/mol
−436.8 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Inhalation hazards
Irritant
GHS labelling:
Danger
H315, H319, H335
P261, P305+P351+P338
NFPA 704 (fire diamond)
0
0
0
Lethal dose or concentration (LD, LC):
3.73 g/kg (mice, oral)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Silver carbonate is the chemical compound with the formula Ag2CO3. This salt is yellow but typical samples are grayish due to the presence of elemental silver. It is poorly soluble in water, like most transition metal carbonates.