Silicon tetrafluoride
| Names | |
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| IUPAC names
Tetrafluorosilane
Silicon tetrafluoride | |
| Other names
Silicon fluoride
Fluoro acid air | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.029.104 |
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PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 1859 |
CompTox Dashboard (EPA)
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| Properties | |
| SiF4 | |
| Molar mass | 104.0791 g/mol |
| Appearance | colourless gas, fumes in moist air |
| Density | 1.66 g/cm3, solid (−95 °C) 4.69 g/L (gas) |
| Melting point | −95.0 °C (−139.0 °F; 178.2 K) |
| Boiling point | −90.3 °C (−130.5 °F; 182.8 K) |
| Critical point (T, P) | −14.15 °C (6.5 °F; 259.0 K), 36.71 standard atmospheres (3,719.6 kPa; 539.5 psi) |
| decomposes | |
| Structure | |
| tetrahedral | |
| 0 D | |
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
Main hazards
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toxic, corrosive |
| GHS labelling:[1] | |
| Danger | |
| H280, H300, H310, H314, H330, H331 | |
| P260, P262, P264, P270, P271, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P330, P361+P364, P363, P403+P233, P405, P410+P403, P501 Preview warning: Omit Rules: keep P260, omit P261
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| NFPA 704 (fire diamond) | |
| Lethal dose or concentration (LD, LC): | |
LCLo (lowest published)
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69.220 mg/m3 (rat, 4 hr) |
| Safety data sheet (SDS) | ICSC 0576 |
| Related compounds | |
Other anions
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Silicon tetrachloride Silicon tetrabromide Silicon tetraiodide |
Other cations
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Carbon tetrafluoride Germanium tetrafluoride Tin tetrafluoride Lead tetrafluoride |
Related compounds
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Hexafluorosilicic acid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Silicon tetrafluoride or tetrafluorosilane is a chemical compound with the formula SiF4. This colorless gas is notable for having a narrow liquid range: its boiling point is only 4 °C above its melting point. It was first prepared in 1771 by Carl Wilhelm Scheele by dissolving silica in hydrofluoric acid, and later synthesized by John Davy in 1812. It is a tetrahedral molecule and is corrosive.