Potassium permanganate
| Names | |
|---|---|
| IUPAC name
Potassium manganate(VII)
| |
| Systematic IUPAC name
Potassium permanganate | |
Other names
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| Identifiers | |
3D model (JSmol)
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| ChEBI | |
| ChEMBL | |
| ChemSpider | |
| DrugBank | |
| ECHA InfoCard | 100.028.874 |
| EC Number |
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| KEGG | |
PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 1490 |
CompTox Dashboard (EPA)
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| Properties | |
| KMnO4 | |
| Molar mass | 158.032 g·mol−1 |
| Appearance | Purplish-bronze-gray needles purple in solution |
| Odor | odorless |
| Density | 2.7 g/cm3 |
| Melting point | 240 °C (464 °F; 513 K) (decomposes) |
| 76 g/L (25 °C) 250 g/L (65 °C) | |
| Solubility | soluble in organic solvents; decomposes in alcohol |
| +20.0·10−6 cm3/mol | |
Refractive index (nD)
|
1.59 |
| Structure | |
| Orthorhombic, oP24 | |
| Pnma, No. 62 | |
a = 0.909 nm, b = 0.572 nm, c = 0.741 nm
| |
Formula units (Z)
|
4 |
| Thermochemistry | |
Heat capacity (C)
|
119.2 J/mol K |
Std molar
entropy (S⦵298) |
171.7 J K−1 mol−1 |
Std enthalpy of
formation (ΔfH⦵298) |
−813.4 kJ/mol |
Gibbs free energy (ΔfG⦵)
|
−713.8 kJ/mol |
| Pharmacology | |
| D08AX06 (WHO) V03AB18 (WHO) | |
| Hazards | |
| GHS labelling: | |
| NFPA 704 (fire diamond) | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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1090 mg/kg (oral, rat) |
| Related compounds | |
Other anions
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Potassium pertechnetate Potassium perrhenate |
Other cations
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Sodium permanganate Ammonium permanganate Calcium permanganate Silver permanganate |
Related manganates
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Potassium hypomanganate Potassium manganate |
Related compounds
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Manganese heptoxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and MnO−
4 ions to give an intensely pink to purple solution.
Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also traditionally as a medication for dermatitis, for cleaning wounds, and general disinfection. It is on the World Health Organization's List of Essential Medicines. It has a great variety of niche uses such as biocide for water treatment purposes and for tanning and dyeing cloth. In 2000, worldwide production was estimated at 30,000 tons.
It is also referred to as chameleon mineral, Condy's crystals, permanganate of potash, hypermangan, purple potion powder, permanganic acid (potassium salt), and purple salt.