Potassium permanganate

Potassium permanganate
Names
IUPAC name
Potassium manganate(VII)
Systematic IUPAC name
Potassium permanganate
Other names
  • Chameleon mineral
  • Condy's crystals
  • Permanganate of potash
  • Hypermangan
  • Purple potion powder
  • Permanganic acid, potassium salt
  • Purple salt
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.028.874
EC Number
  • 231-760-3
KEGG
RTECS number
  • SD6475000
UNII
UN number 1490
  • InChI=1S/K.Mn.4O/q+1;;;;;-1 Y
    Key: VZJVWSHVAAUDKD-UHFFFAOYSA-N Y
  • [K+].[O-][Mn](=O)(=O)=O
Properties
KMnO4
Molar mass 158.032 g·mol−1
Appearance Purplish-bronze-gray needles
purple in solution
Odor odorless
Density 2.7 g/cm3
Melting point 240 °C (464 °F; 513 K) (decomposes)
76 g/L (25 °C)
250 g/L (65 °C)
Solubility soluble in organic solvents; decomposes in alcohol
+20.0·10−6 cm3/mol
1.59
Structure
Orthorhombic, oP24
Pnma, No. 62
a = 0.909 nm, b = 0.572 nm, c = 0.741 nm
4
Thermochemistry
119.2 J/mol K
171.7 J K−1 mol−1
−813.4 kJ/mol
−713.8 kJ/mol
Pharmacology
D08AX06 (WHO) V03AB18 (WHO)
Hazards
GHS labelling:
NFPA 704 (fire diamond)
Lethal dose or concentration (LD, LC):
1090 mg/kg (oral, rat)
Related compounds
Other anions
Potassium pertechnetate
Potassium perrhenate
Other cations
Sodium permanganate
Ammonium permanganate
Calcium permanganate
Silver permanganate
Related manganates
Potassium hypomanganate
Potassium manganate
Related compounds
Manganese heptoxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and MnO
4
ions to give an intensely pink to purple solution.

Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also traditionally as a medication for dermatitis, for cleaning wounds, and general disinfection. It is on the World Health Organization's List of Essential Medicines. It has a great variety of niche uses such as biocide for water treatment purposes and for tanning and dyeing cloth. In 2000, worldwide production was estimated at 30,000 tons.

It is also referred to as chameleon mineral, Condy's crystals, permanganate of potash, hypermangan, purple potion powder, permanganic acid (potassium salt), and purple salt.