Phycoerythrobilin

Phycoerythrobilin
(3E)-phycoerythrobilin
Names
IUPAC name
(2R,3E,16R)-18-ethenyl-3-ethylidene-1,2,3,15,16,19,22,24-octahydro-2,7,13,17-tetramethyl-1,19-dioxo-21H-biline-8,12-dipropanoic Acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
MeSH phycoerythrobilin
  • InChI=1S/C33H38N4O6/c1-7-20-19(6)32(42)37-27(20)14-25-18(5)23(10-12-31(40)41)29(35-25)15-28-22(9-11-30(38)39)17(4)24(34-28)13-26-16(3)21(8-2)33(43)36-26/h7-8,14-15,19,26,35H,2,9-13H2,1,3-6H3,(H,36,43)(H,37,42)(H,38,39)(H,40,41)/b20-7+,27-14-,28-15-/t19-,26-/m1/s1 Y
    Key: IGJXAXFFKKRFKU-NDGVYKEISA-N Y
  • C=CC1=C(C)[C@@H](CC2=N/C(=C\c3[nH]c(/C=C4\NC(=O)[C@H](C)\C4=C/C)c(C)c3CCC(=O)O)C(CCC(=O)O)=C2C)NC1=O
Properties
C33H38N4O6
Molar mass 586.689 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Phycoerythrobilin is a red phycobilin, i.e. an open tetrapyrrole chromophore found in cyanobacteria and in the chloroplasts of red algae, glaucophytes and some cryptomonads. Phycoerythrobilin is present in the phycobiliprotein phycoerythrin, of which it is the terminal acceptor of energy. The amount of phycoerythrobilin in phycoerythrins varies, depending on the organism. In some Rhodophytes and oceanic cyanobacteria, phycoerythrobilin is also present in the phycocyanin, then termed R-phycocyanin. Like all phycobilins, phycoerythrobilin is covalently linked to these phycobiliproteins by a thioether bond.

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