(Bis(trifluoroacetoxy)iodo)benzene

(Bis(trifluoroacetoxy)iodo)­benzene
Names
Preferred IUPAC name
1,1′-[(Phenyl-λ3-iodanediyl)bis(oxy)]bis(2,2,2-trifluoroethan-1-one)
Other names
Phenyliodine bis(trifluoroacetate); PIFA
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.018.462
EC Number
  • 220-308-0
UNII
  • InChI=1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H Y
    Key: PEZNEXFPRSOYPL-UHFFFAOYSA-N Y
  • InChI=1/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H
    Key: PEZNEXFPRSOYPL-UHFFFAOYAA
  • FC(F)(F)C(=O)OI(OC(=O)C(F)(F)F)c1ccccc1
Properties
C10H5F6IO4
Molar mass 430.041 g·mol−1
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

(Bis(trifluoroacetoxy)iodo)benzene, C
6
H
5
I(OCOCF
3
)
2
, is a hypervalent iodine compound used as a reagent in organic chemistry. It can be used to carry out the Hofmann rearrangement under acidic conditions.