Paris green

Paris green
A subunit of the Cu(C2H3O2)2·3Cu(AsO2)2 framework, highlighting the As3O3−6 ligand. Color code: Cu = blue, As = large gray, C = gray, O = red.
Names
Other names
  • C.I. pigment green 21
  • Emerald green
  • Imperial green
  • Mitis green
  • Schweinfurt green
  • Veronese green
  • Vienna green
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.125.242
EC Number
  • 601-658-7
UNII
UN number 1585
  • InChI=1S/2C2H4O2.6AsHO2.4Cu/c2*1-2(3)4;6*2-1-3;;;;/h2*1H3,(H,3,4);6*(H,2,3);;;;/q;;;;;;;;4*+2/p-8
    Key: HTSABAUNNZLCMN-UHFFFAOYSA-F
  • CC(=O)[O-].CC(=O)[O-].[O-][As]=O.[O-][As]=O.[O-][As]=O.[O-][As]=O.[O-][As]=O.[O-][As]=O.[Cu+2].[Cu+2].[Cu+2].[Cu+2]
  • CC(=O)[O-].CC(=O)[O-].[O-][As]0O[As]([O-])O[As]([O-])O0.[O-][As]0O[As]([O-])O[As]([O-])O0.[Cu+2].[Cu+2].[Cu+2].[Cu+2]
Properties
Cu(C2H3O2)2·3Cu(AsO2)2
Molar mass 1013.79444 g⋅mol−1
Appearance Emerald green crystalline powder
Density >1.1 g/cm3 (20 °C (68 °F; 293 K))
Melting point > 345 °C (653 °F; 618 K)
Boiling point decomposes
insoluble
Hazards
GHS labelling:
Danger
H300, H313, H331, H411
P261, P264, P273, P280, P301+P310, P304+P340
NFPA 704 (fire diamond)
4
1
0
Lethal dose or concentration (LD, LC):
22 mg/kg
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.01 mg/m3 (as As)
REL (Recommended)
0.002 mg/m3 (15-minute, as As)
IDLH (Immediate danger)
5 mg/m3 (as As)]
Safety data sheet (SDS) Toronto Research Chemicals SDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
Paris green
 
    Color coordinates
Hex triplet#50C878
sRGBB (r, g, b)(80, 200, 120)
HSV (h, s, v)(140°, 60%, 78%)
CIELChuv (L, C, h)(72, 71, 137°)
SourceMaerz and Paul
ISCC–NBS descriptorVivid yellowish green
B: Normalized to [0–255] (byte)

Paris green (copper(II) acetate triarsenite or copper(II) acetoarsenite) is an arsenic- and copper-containing pigment. It is an emerald-green crystalline powder that is also known as Mitis green, Schweinfurt green, Sattler green, emerald green, Vienna green, emperor green or mountain green. It is highly toxic and has thus also been used as a rodenticide and insecticide. Its formula is Cu(C2H3O2)2·3Cu(AsO2)2.

It was manufactured in 1814 to be a pigment to make a vibrant green paint, and was used by many notable painters in the 19th century. The color of Paris green is said to range from a pale blue-green when very finely ground, to a deeper green when coarsely ground. Due to the presence of arsenic, the pigment is extremely toxic. In paintings, the color can degrade quickly.