Oxone

Oxone
2(K+HSO5)·K+HSO4·(K+)2SO2−4
Names
IUPAC name
Potassium peroxysulfate-potassium sulfate-potassium bisulfate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 274-778-7
  • 609-357-2
UNII
  • InChI=1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
    Key: HJKYXKSLRZKNSI-UHFFFAOYSA-I
  • OS(=O)(=O)[O-].OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].[O-]S(=O)(=O)[O-].[K+].[K+].[K+].[K+].[K+]
Properties
H3K5O18S4
Molar mass 614.76 g/mol
Appearance white solid
Melting point 250 °C (482 °F; 523 K) (Decomposes)
25-30 % (w/v) at 22 °C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidant, corrosive
GHS labelling:
Danger
H302, H314, H412
P273, P280, P301+P330+P331, P303+P361+P353, P305+P351+P338, P310
NFPA 704 (fire diamond)
3
0
1
Safety data sheet (SDS) ECHA
Related compounds
Related compounds
Potassium persulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Oxone is the triple salt 2KHSO5·KHSO4·K2SO4. For almost all applications, the active ingredient in this compound is potassium peroxymonosulfate, KHSO5. The triple salt has a longer shelf-life than potassium peroxymonosulfate, but releases the same peroxymonosulfate anion upon dissolution.

One advantage of oxone from an industrial point of view is that its dangerous goods classification tends to be Corrosive (Class 8) rather than Oxidising (Class 5). This makes it easier and cheaper to transport compared to other persulfate salts.