Nitrosylsulfuric acid

Nitrosylsulfuric acid
Names
IUPAC name
Nitrosylsulfuric acid
Other names
nitrosonium bisulfate, chamber crystals
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.058
UNII
  • InChI=1S/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5) Y
    Key: VQTGUFBGYOIUFS-UHFFFAOYSA-N Y
  • InChI=1/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5)
    Key: VQTGUFBGYOIUFS-UHFFFAOYAM
  • O=NOS(=O)(=O)O
Properties
NOHSO4
Molar mass 127.08 g/mol
Appearance Pale yellow crystals
Density 1.865 g/mL in
40% sulfuric acid soln
Melting point 70 °C (158 °F; 343 K)
Boiling point Decomposes
Decomposes
Solubility Soluble in H2SO4
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidizer
Related compounds
Other anions
NOCl
Other cations
NaHSO4
Related compounds
NOBF4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Nitrosylsulfuric acid is the chemical compound with the formula NOHSO4. It is a colourless solid that is used industrially in the production of caprolactam, and was formerly part of the lead chamber process for producing sulfuric acid. The compound is a salt best described as NO+HSO4 (nitrosonium hydrogensulfate). It is called “lead-chamber crystals”.

In organic chemistry, it is used as a reagent for nitrosating, as a diazotizing agent, and as an oxidizing agent.