N-Methylaniline
| Names | |
|---|---|
| Preferred IUPAC name
N-Methylaniline | |
| Other names
N-methylbenzenamine
N-Monomethylaniline Anilinomethane N-phenylmethylamine Monomethylaniline N-methylaminobenzene Methylbenzeneamine N-Methyl-phenylamine (methylamino) benzene | |
| Identifiers | |
3D model (JSmol)
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| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.002.610 |
| EC Number |
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| KEGG | |
PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 2294 |
CompTox Dashboard (EPA)
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| Properties | |
| C7H9N | |
| Molar mass | 107.156 g·mol−1 |
| Appearance | colorless liquid |
| Odor | weak, ammonia-like |
| Density | 0.99 g/mL |
| Melting point | −57 °C (−71 °F; 216 K) |
| Boiling point | 194 to 196 °C (381 to 385 °F; 467 to 469 K) |
| Insoluble | |
| Vapor pressure | 0.3 mmHg (20 °C) |
| −82.74·10−6 cm3/mol | |
| Hazards | |
| GHS labelling: | |
| Danger | |
| H301, H311, H331, H373, H410 | |
| P260, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P311, P312, P314, P321, P322, P330, P361, P363, P391, P403+P233, P405, P501 Preview warning: Omit Rules: keep P260, omit P261
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| Flash point | 79 °C; 175 °F; 353 K |
| Lethal dose or concentration (LD, LC): | |
LDLo (lowest published)
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280 mg/kg (rabbit, oral) 1200 mg/kg (guinea pig, oral) |
| NIOSH (US health exposure limits): | |
PEL (Permissible)
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TWA 2 ppm (9 mg/m3) [skin] |
REL (Recommended)
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TWA 0.5 ppm (2 mg/m3) [skin] |
IDLH (Immediate danger)
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100 ppm |
| Related compounds | |
Related aromatic amines
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Aniline Dimethylaniline |
Related compounds
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Toluidines |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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N-Methylaniline (NMA) is an aniline derivative. It is an organic compound with the chemical formula C6H5NH(CH3). The substance is a colorless viscous liquid, Samples turn brown when exposed to air. The chemical is insoluble in water. It is used as a latent and coupling solvent and is also used as an intermediate for dyes, agrochemicals and other organic products manufacturing. NMA is toxic and exposure can cause damage to the central nervous system and can also cause liver and kidney failure. The comprehensive evaluation of N-methylaniline by the Bureau for Chemical Substances in Poland, completed in 2024 as a part of the European Union's REACH regulation, has confirmed significant concerns regarding the carcinogenicity and mutagenicity of N-methylaniline.