Methyl dihydrojasmonate

Methyl dihydrojasmonate
Names
Preferred IUPAC name
Methyl 2-(3-oxo-2-pentylcyclopentyl)acetate
Other names
Hedione
Kharismal
Cepionate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.042.254
EC Number
  • 246-495-9
UNII
  • InChI=1S/C13H22O3/c1-3-4-5-6-11-10(7-8-12(11)14)9-13(15)16-2/h10-11H,3-9H2,1-2H3
    Key: KVWWIYGFBYDJQC-UHFFFAOYSA-N
  • O=C(OC)CC1C(C(=O)CC1)CCCCC
Properties
C13H22O3
Molar mass 226.316 g·mol−1
Appearance Clear to pale yellow oily liquid
Boiling point 307.8 °C (586.0 °F; 581.0 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable
Flash point 113 °C (235 °F; 386 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Methyl dihydrojasmonate (often referred to by its trade names of hedione or kharismal) is an aroma compound with an odor similar to that of jasmine. It is a synthetic relative of methyl jasmonate, a naturally occurring compound in floral scents such as jasmine, tuberose and magnolia. In racemic mixtures the odor is floral and citrus, while epimerized mixtures exhibit a dense buttery-floral odor with odor recognition thresholds of 15 parts per billion. Considered one of the compounds responsible for the projection of the scent in living flowers, it was first fully characterised and synthesized between 1957 and 1962 in jasmine absolute (0.8%) by the fragrance chemist Edouard Demole, who was working at Firmenich. and is used in fine fragrances as well as cosmetics, toiletries, and detergents.