Methanesulfonyl chloride

Methanesulfonyl chloride
Names
Preferred IUPAC name
Methanesulfonyl chloride
Other names
Mesyl chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.279
EC Number
  • 204-706-1
UNII
UN number 3246
  • InChI=1S/CH3ClO2S/c1-5(2,3)4/h1H3
    Key: QARBMVPHQWIHKH-UHFFFAOYSA-N
  • CS(Cl)(=O)=O
Properties
CH3SO2Cl
Molar mass 114.54 g·mol−1
Appearance colorless liquid
Odor Pungent, unpleasant
Density 1.480 g/cm3
Melting point −32 °C (−26 °F; 241 K)
Boiling point 161 °C (322 °F; 434 K) (at 730 mmHg)
Reacts
Solubility Soluble in alcohol, ether and most organic solvents
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Lachrymator, highly toxic, corrosive
GHS labelling:[1]
Danger
H290, H300, H301, H302, H311, H312, H314, H317, H330, H335, H412
P234, P260, P262, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P333+P317, P361+P364, P362+P364, P363, P390, P403+P233, P405, P501
Preview warning: Omit Rules: keep P234, omit P406
Preview warning: Omit Rules: keep P260, omit P261
Flash point >110 °C (230 °F; 383 K)
Related compounds
Other anions
Methanesulfonyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Methanesulfonyl chloride (mesyl chloride) is an organosulfur compound with the formula CH3SO2Cl. Using the organic pseudoelement symbol Ms for the methanesulfonyl (or mesyl) group CH3SO2–, it is frequently abbreviated MsCl in reaction schemes or equations. It is a colourless liquid that dissolves in polar organic solvents but is reactive toward water, alcohols, and many amines. The simplest organic sulfonyl chloride, it is used to make methanesulfonates and to generate the elusive molecule sulfene (methylenedioxosulfur(VI)).