Methacrylonitrile

Methacrylonitrile
Names
Preferred IUPAC name
2-Methylprop-2-enenitrile
Other names
Methylacrylonitrile
2-Cyanopropene
2-Cyano-1-propene
Isopropenecyanide
Isopropenylcyanid
Isopropene cyanide
Identifiers
3D model (JSmol)
Abbreviations MeAN
ChEMBL
ChemSpider
ECHA InfoCard 100.004.380
EC Number
  • 204-817-5
RTECS number
  • UD1400000
UNII
UN number 3079
  • InChI=1S/C4H5N/c1-4(2)3-5/h1H2,2H3
    Key: GYCMBHHDWRMZGG-UHFFFAOYSA-N
  • C=C(C)C#N
Properties
C4H5N
Molar mass 67.091 g·mol−1
Appearance Clear colorless to very slightly yellow liquid
Odor Bitter almonds
Density 0.8 g/mL
Melting point −35.8 °C (−32.4 °F; 237.3 K)
Boiling point 90 to 92 °C (194 to 198 °F; 363 to 365 K)
2.57 g/100 mL (20 °C)
Vapor pressure 71 mmHg (25 °C)
Hazards
GHS labelling:
Danger
H225, H301, H311, H317, H331
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P272, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P311, P312, P321, P322, P330, P333+P313, P361, P363, P370+P378, P403+P233, P403+P235, P405, P501
Flash point 13 °C (55 °F; 286 K)
Explosive limits 2%-6.8%
NIOSH (US health exposure limits):
PEL (Permissible)
none
REL (Recommended)
TWA 1 ppm (3 mg/m3) [skin]
IDLH (Immediate danger)
N.D.
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Methacrylonitrile (or 2-Methylprop-2-enenitrile), MeAN in short, is a chemical compound that is an unsaturated aliphatic nitrile, widely used in the preparation of homopolymers, copolymers, elastomers, and plastics and as a chemical intermediate in the preparation of acids, amides, amines, esters, and other nitriles. MeAN is also used as a replacement for acrylonitrile in the manufacture of an acrylonitrile/butadiene/styrene-like polymer. It is a clear and colorless (to slightly yellow) liquid, that has a bitter almond smell.

It is toxic by ingestion, inhalation, and skin absorption.