Lead(II) iodide

Lead(II) iodide
Names
Other names
Plumbous iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.220
EC Number
  • 233-256-9
UNII
UN number 2291 3077
  • InChI=1S/2HI.Pb/h2*1H;/q;;+2/p-2 Y
    Key: RQQRAHKHDFPBMC-UHFFFAOYSA-L Y
  • InChI=1/2HI.Pb/h2*1H;/q;;+2/p-2
    Key: RQQRAHKHDFPBMC-NUQVWONBAP
  • I[Pb]I
Properties
PbI
2
Molar mass 461.01 g/mol
Appearance bright yellow powder
Odor odorless
Density 6.16 g/cm3
Melting point 410 °C (770 °F; 683 K)
Boiling point 872 °C (1,602 °F; 1,145 K) decomp.
  • 0.44 g/L (0 °C)
  • 0.76 g/L (20 °C)
  • 4.1 g/L (100 °C)
4.41×10−9 (20 °C)
Solubility
Band gap 2.34 eV (direct)
−126.5·10−6 cm3/mol
Structure
Hexagonal hP6
P63mc, No. 186
a = 0.4556 nm, b = 0.4556 nm, c = 1.3973 nm
α = 90°, β = 90°, γ = 120°°
2
octahedral
Thermochemistry
77.4 J/(mol·K)
174.9 J/(mol·K)
−175.5 kJ/mol
−173.6 kJ/mol
Hazards
GHS labelling:
Danger
H302, H332, H360, H373, H410
P201, P202, P260, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P391, P405, P501
Preview warning: Omit Rules: keep P260, omit P261
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
Related compounds
Other anions
Other cations
Tin(II) iodide
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Lead(II) iodide (or lead iodide) is a chemical compound with the formula PbI
2
. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.

The compound currently has a few specialized applications, such as the manufacture of solar cells, X-rays and gamma-ray detectors. Its preparation is used in chemistry education to teach topics such as precipitation reactions and stoichiometry. It is decomposed by light at temperatures above 125 °C (257 °F), and this effect has been used in a patented photographic process.

Lead iodide was formerly employed as a yellow pigment in some paints, with the name iodide yellow. However, that use has been largely discontinued due to its toxicity and poor stability.