Lead(II) iodide
| Names | |
|---|---|
| Other names
Plumbous iodide
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.030.220 |
| EC Number |
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PubChem CID
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| UNII | |
| UN number | 2291 3077 |
CompTox Dashboard (EPA)
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| Properties | |
| PbI 2 | |
| Molar mass | 461.01 g/mol |
| Appearance | bright yellow powder |
| Odor | odorless |
| Density | 6.16 g/cm3 |
| Melting point | 410 °C (770 °F; 683 K) |
| Boiling point | 872 °C (1,602 °F; 1,145 K) decomp. |
| |
Solubility product (Ksp)
|
4.41×10−9 (20 °C) |
| Solubility |
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| Band gap | 2.34 eV (direct) |
| −126.5·10−6 cm3/mol | |
| Structure | |
| Hexagonal hP6 | |
| P63mc, No. 186 | |
a = 0.4556 nm, b = 0.4556 nm, c = 1.3973 nm α = 90°, β = 90°, γ = 120°°
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Formula units (Z)
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2 |
| octahedral | |
| Thermochemistry | |
Heat capacity (C)
|
77.4 J/(mol·K) |
Std molar
entropy (S⦵298) |
174.9 J/(mol·K) |
Std enthalpy of
formation (ΔfH⦵298) |
−175.5 kJ/mol |
Gibbs free energy (ΔfG⦵)
|
−173.6 kJ/mol |
| Hazards | |
| GHS labelling: | |
| Danger | |
| H302, H332, H360, H373, H410 | |
| P201, P202, P260, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P391, P405, P501 Preview warning: Omit Rules: keep P260, omit P261
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| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Related compounds | |
Other anions
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Other cations
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Tin(II) iodide |
Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Lead(II) iodide (or lead iodide) is a chemical compound with the formula PbI
2. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.
The compound currently has a few specialized applications, such as the manufacture of solar cells, X-rays and gamma-ray detectors. Its preparation is used in chemistry education to teach topics such as precipitation reactions and stoichiometry. It is decomposed by light at temperatures above 125 °C (257 °F), and this effect has been used in a patented photographic process.
Lead iodide was formerly employed as a yellow pigment in some paints, with the name iodide yellow. However, that use has been largely discontinued due to its toxicity and poor stability.