Iron(II) oxalate

Iron(II) oxalate
Names
IUPAC name
Iron(II) oxalate
Systematic IUPAC name
Iron, diaqua(ethanedioato(2-)-O,O')- (dihydrate)
Other names
  • Iron oxalate
  • Ferrous oxalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.472
EC Number
  • (anhydrous): 208-217-4
  • (dihydrate): 611-981-5
UNII
  • InChI=1S/3C2H2O4.2Fe/c3*3-1(4)2(5)6;;/h3*(H,3,4)(H,5,6);;/q;;;2*+3/p-6 N
    Key: VEPSWGHMGZQCIN-UHFFFAOYSA-H N
  • (dihydrate): InChI=1S/C2H2O4.Fe.2H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);;2*1H2/q;+2;;/p-2
    Key: NPLZZSLZTJVZSX-UHFFFAOYSA-L
  • (anhydrous): [Fe+2].O=C([O-])-C([O-])=O
  • (dihydrate): C(=O)(C(=O)[O-])[O-].O.O.[Fe+2]
Properties
  • FeC2O4 (anhydrous)
  • FeC2O4·2H2O (dihydrate)
Molar mass
  • 143.86 g⋅mol−1 (anhydrous)
  • 179.89 g⋅mol−1 (dihydrate)
Appearance yellow powder
Odor odorless
Density 2.28 g/cm3
Melting point
  • ~120 °C (248 °F; 393 K) (dihydrate, decomposes to anhydrous)
  • 190 °C (374 °F; 463 K) (anhydrous, decomposes)
0.097 g/100g (dihydrate)
Hazards
GHS labelling:
Warning
H302+H312
P264, P270, P280, P301+P312+P330, P302+P352+P312, P363, P501
NFPA 704 (fire diamond)
2
1
1
1 mg/m3 (TWA)
NIOSH (US health exposure limits):
PEL (Permissible)
1 mg/m3 (TWA, vacated)
REL (Recommended)
1 mg/m3 (TWA)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Ferrous oxalate (iron(II) oxalate) refers to the inorganic compound with the formula FeC2O4 (anhydrous) or FeC2O4·2H2O (dihydrate). These are yellow compounds. Characteristic of metal oxalate complexes, these compounds tend to be polymeric, hence their low solubility in water. The dihydrate is hygroscopic.