Gold(I) chloride

Gold(I) chloride
Names
IUPAC name
Gold(I) chloride
Other names
Aurous chloride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.583
UNII
  • InChI=1S/Au.ClH/h;1H/q+1;/p-1 Y
    Key: FDWREHZXQUYJFJ-UHFFFAOYSA-M Y
  • InChI=1/Au.ClH/h;1H/q+1;/p-1
    Key: FDWREHZXQUYJFJ-REWHXWOFAM
  • [Au]Cl
Properties
AuCl
Molar mass 232.423 g/mol
Appearance yellow solid
Density 7.6 g/cm3
Melting point 210 °C (410 °F; 483 K) (decomposition)
Insoluble (cold water)
Reacts (warm water)
Solubility Soluble in HCl, HBr organic solvents
−67.0·10−6 cm3/mol
Structure
Tetragonal, tI16
I41/amd, No. 141
a = 6.734 Å, c = 8.674 Å
Thermochemistry
–34.7 kJ/mol
Hazards
GHS labelling:
Danger
H314, H317
NFPA 704 (fire diamond)
3
1
0
Safety data sheet (SDS) MSDS (Fisher)
Related compounds
Other anions
Gold(I) fluoride
Gold(I) bromide
Gold(I) iodide
Other cations
Copper(I) chloride
Silver chloride
Related compounds
Gold(I,III) chloride
Gold(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Gold(I) chloride is a compound of gold and chlorine with the chemical formula AuCl. It is a metastable yellow solid that hydrolyses in warm water and decomposes to gold and chlorine gas at elevated temperatures. It has limited uses in organic chemistry as a Lewis acid.