Gallium(III) oxide

Gallium(III) trioxide
β-Ga2O3 crystal
Crystal structure of β-Ga2O3
Names
Other names
gallium trioxide, gallium sesquioxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.525
EC Number
  • 234-691-7
RTECS number
  • LW9650000
UNII
  • InChI=1S/2Ga.3O Y
    Key: QZQVBEXLDFYHSR-UHFFFAOYSA-N Y
  • InChI=1/2Ga.3O/rGa2O3/c3-1-5-2-4
    Key: QZQVBEXLDFYHSR-OGCFUIRMAC
  • O=[Ga]O[Ga]=O
Properties
Ga2O3
Molar mass 187.444 g/mol
Appearance white crystalline powder
Melting point 1,725 °C (3,137 °F; 1,998 K)
insoluble
Solubility soluble in most acids
Structure
Monoclinic, mS20, space group = C2/m, No. 12
a = 1.2232 nm, b = 0.3041 nm, c = 0.5801 nm
α = 90°, β = 103.73°, γ = 90°
β-phase
4
Thermochemistry
92.1 J/(mol·K)
85.0 J/(mol·K)
−1089.1 kJ/mol
−998.3 kJ/mol
Enthalpy of fusion fHfus)
100 kJ/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Gallium(III) oxide is an inorganic compound with the formula Ga2O3. An ultra-wide-bandgap semiconductor, it has been studied for applications in power electronics, phosphors, and gas sensing. The compound has several polymorphs, of which the monoclinic β-phase is the most stable.