Fluoroantimonic acid
Fluoroantimonic acid stored in a PFA bottle
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| Names | |
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| IUPAC name
Fluoroantimonic acid
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| Systematic IUPAC name
Hexafluoroantimonic acid | |
Other names
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| Identifiers | |
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3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.037.279 |
| EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Molar mass | 236.756 g/mol |
| Appearance | Colorless liquid |
| Density | 2.885 g/cm3 |
| Boiling point | 40 °C (104 °F; 313 K) (decomposes) |
| Reacts with water | |
| Solubility in sulfuryl chloride fluoride | soluble |
| Solubility in sulfur dioxide | soluble |
| Vapor pressure | 19 hPa (18 °C (64 °F; 291 K)) |
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
Main hazards
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Extremely corrosive, toxic, reacts violently with water. |
| GHS labelling: | |
| Danger | |
| H300+H310+H330, H314, H411 | |
| P260, P262, P264, P270, P271, P273, P280, P284, P301+P310+P330, P301+P330+P331, P302+P350, P303+P361+P353, P304+P340+P310, P305+P351+P338+P310, P362, P391, P403+P233, P405, P501 | |
| NFPA 704 (fire diamond) | |
Threshold limit value (TLV)
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0.5 mg/m3 (TWA) |
| NIOSH (US health exposure limits): | |
PEL (Permissible)
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0.5 mg/m3 |
REL (Recommended)
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0.5 mg/m3 (TWA) |
| Related compounds | |
Related acids
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions, the simplest being fluoronium (H2F+) and fluoroantimonate (SbF−6). The mixture is the strongest known superacid, stronger than pure sulfuric acid by many orders of magnitude, according to its Hammett acidity function. It even protonates some hydrocarbons to afford pentacoordinate carbocations (carbonium ions). Like its precursor hydrogen fluoride, it attacks glass, but can be stored in containers lined with PTFE (Teflon) or PFA.