Fluoroantimonic acid

Fluoroantimonic acid
Fluoroantimonic acid stored in a PFA bottle
Names
IUPAC name
Fluoroantimonic acid
Systematic IUPAC name
Hexafluoroantimonic acid
Other names
  • Fluoroantimonic(V) acid
  • Hydrogen Fluoroantimonate
  • Hydrogen Hexafluoroantimonate
  • Fluoronium Fluoroantimonate
  • Fluoronium Hexafluoroantimonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.279
EC Number
  • 241-023-8
  • InChI=1S/FH2.6FH.Sb/h1H2;6*1H;/q+1;;;;;;;+5/p-6 N
    Key: HBGBSIVYTBPVEU-UHFFFAOYSA-H N
  • [FH2+].F[Sb-](F)(F)(F)(F)F
Properties
Molar mass 236.756 g/mol
Appearance Colorless liquid
Density 2.885 g/cm3
Boiling point 40 °C (104 °F; 313 K) (decomposes)
Reacts with water
Solubility in sulfuryl chloride fluoride soluble
Solubility in sulfur dioxide soluble
Vapor pressure 19 hPa (18 °C (64 °F; 291 K))
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Extremely corrosive, toxic, reacts violently with water.
GHS labelling:
Danger
H300+H310+H330, H314, H411
P260, P262, P264, P270, P271, P273, P280, P284, P301+P310+P330, P301+P330+P331, P302+P350, P303+P361+P353, P304+P340+P310, P305+P351+P338+P310, P362, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
0.5 mg/m3 (TWA)
NIOSH (US health exposure limits):
PEL (Permissible)
0.5 mg/m3
REL (Recommended)
0.5 mg/m3 (TWA)
Related compounds
Related acids
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions, the simplest being fluoronium (H2F+) and fluoroantimonate (SbF6). The mixture is the strongest known superacid, stronger than pure sulfuric acid by many orders of magnitude, according to its Hammett acidity function. It even protonates some hydro­carbons to afford pentacoordinate carbo­cations (carbonium ions). Like its precursor hydrogen fluoride, it attacks glass, but can be stored in containers lined with PTFE (Teflon) or PFA.