Desaurin
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| IUPAC name
2,4-dimethylidene-1,3-dithietane
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3D model (JSmol)
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PubChem CID
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Desaurins are a type of sulfur-containing heterocycle. The parent is 2,4-bismethylene-1,3-dithietane. They are derived from the base-promoted condensation of carbon disulfide with "active methylene" compounds:
- 2 Z2CH2 + 2 CS2 → Z2C=CS2C=CZ2 + 2 H2S
According to X-ray crystallography, the C4S2 core of desaurins is planar. With unsymmetrical substitution (at the ends of the methylene groups), they can exist as separable cis and trans isomers.