Copper peroxide

Copper(II) peroxide
Names
IUPAC name
Copper(II) peroxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cu.O2/c;1-2/q+2;-2
    Key: CNBDXDKFMUKCIQ-UHFFFAOYSA-N
  • [Cu+2].[O-][O-]
Properties
Cu(O2)
Molar mass 95.945 g/mol
Appearance Various
Related compounds
Related compounds
Copper(IV) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Copper peroxide is an inorganic compound with the chemical formula Cu(O2). The 1:2 ratio of copper and oxygen would be consistent with copper in its common +2 oxidation state and a peroxide group. Cu(O2) has attracted interest from a computational perspective. One highly cited analysis concludes that gaseous Cu(O2) is a superoxide, with copper in a +1 oxidation state: Cu+O2.

Older literature claims that treatment of cold suspended Cu(OH)2 with H2O2 creates a brown hydrate of "copper dioxide," which rapidly decomposes in the presence of water to form ill-defined green and yellow salts above 0 °C.