Chromium trioxide
| Names | |
|---|---|
| IUPAC name
Chromium trioxide
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| Other names
Chromic anhydride, Chromium(VI) oxide, Chromic acid (misnomer)
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| Identifiers | |
3D model (JSmol)
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| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.014.189 |
PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 1463 |
CompTox Dashboard (EPA)
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| Properties | |
| CrO3 | |
| Molar mass | 99.993 g·mol−1 |
| Appearance | Dark red granular solid, deliquescent |
| Odor | Odorless |
| Density | 2.7 g/cm3 (20 °C) |
| Melting point | 197 °C (387 °F; 470 K) |
| Boiling point | 250 °C (482 °F; 523 K) decomposes |
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| Solubility | Soluble in H2SO4, HNO3, (CH3CH2)2O, CH3COOH, (CH3)2CO |
| +40·10−6 cm3/mol | |
| Thermochemistry | |
Std molar
entropy (S⦵298) |
73.2 J/(mol·K) |
Std enthalpy of
formation (ΔfH⦵298) |
−589.3 kJ/mol |
| Hazards | |
| GHS labelling: | |
| Danger | |
| H271, H301+H311, H314, H317, H330, H334, H335, H340, H350, H361f, H372, H410 | |
| P210, P260, P280, P303+P361+P353, P304+P340+P310, P305+P351+P338 | |
| NFPA 704 (fire diamond) | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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80 mg/kg (rats, oral) |
| Safety data sheet (SDS) | ICSC 1194 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is the inorganic compound with the formula CrO3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name.
This compound is a dark-purple solid. Millions of kilograms are produced annually, mainly for electroplating. Chromium trioxide is a powerful oxidiser, a mutagen, and a carcinogen.