Bis(trifluoromethyl)peroxide

Bis(trifluoromethyl)peroxide
Names
Preferred IUPAC name
Trifluoro[(trifluoromethyl)peroxy]methane
Other names
Di(trifluoromethyl)peroxide
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=InChi=1S/C2F6O2/c3-1(4,5)9-10-2(6,7)8
  • C(F)(F)(F)OOC(F)(F)F
Properties
CF3OOCF3
Molar mass 170.010 g·mol−1
Appearance Colorless gas
Density 1.588 g/cm3
Boiling point −37 °C (−35 °F; 236 K)
log P 2.65
Vapor pressure 5180 mmHg
1.231
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Bis(trifluoromethyl)peroxide (BTP) is a fluorocarbon compound with formula CF3OOCF3. It is a colorless toxic gas. This compound was first produced by Frédéric Swarts. It has some utility as a radical initiator for polymerisation reactions. BTP is unusual in the fact that, unlike many peroxides, it is a gas, is non-explosive, and has good thermal stability.