Benzenehexol

Benzenehexol
Names
Preferred IUPAC name
Benzenehexol
Other names
Benzene-1,2,3,4,5,6-hexol
Hexahydroxybenzene
2,3,4,5,6-pentahydroxyphenol
1,2,3,4,5,6-hexahydroxybenzene
Hexaphenol
Fenolão
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.204.877
UNII
  • InChI=1S/C6H6O6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h7-12H Y
    Key: VWPUAXALDFFXJW-UHFFFAOYSA-N Y
  • InChI=1/C6H6O6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h7-12H
    Key: VWPUAXALDFFXJW-UHFFFAOYAU
  • c1(c(c(c(c(c1O)O)O)O)O)O
Properties
C6H6O6
Molar mass 174.108 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Benzenehexol, also called hexahydroxybenzene, is an organic compound with formula C
6
H
6
O
6
or C
6
(OH)
6
. It is a six-fold phenol of benzene. The product is also called hexaphenol, but this name has been used also for other substances.

Benzenehexol is a crystalline solid soluble in hot water, with a melting point above 310°. It can be prepared from inositol (cyclohexanehexol). Oxidation of benzenehexol yields tetrahydroxy-p-benzoquinone (THBQ), rhodizonic acid, and dodecahydroxycyclohexane. Conversely, benzenehexol can be obtained by reduction of sodium THBQ salt with SnCl2/HCl.

Benzenehexol is a starting material for a class of discotic liquid crystals.

Benzenehexol forms an adduct with 2,2'-bipyridine, with 1:2 molecular ratio.