Ammonium dichromate

Ammonium dichromate
Names
IUPAC name
Ammonium dichromate
Other names
Ammonium bichromate
Ammonium pyrochromate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.221
RTECS number
  • HX7650000
UNII
UN number 1439
  • InChI=1S/2Cr.2H3N.7O/h;;2*1H3;;;;;;;/q;;;;;;;;;2*-1/p+2 Y
    Key: JOSWYUNQBRPBDN-UHFFFAOYSA-P Y
  • InChI=1/2Cr.2H3N.7O/h;;2*1H3;;;;;;;/q;;;;;;;;;2*-1/p+2/rCr2O7.2H3N/c3-1(4,5)9-2(6,7)8;;/h;2*1H3/q-2;;/p+2
    Key: JOSWYUNQBRPBDN-RFRSXZKWAS
  • [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O.[NH4+].[NH4+]
Properties
(NH4)2Cr2O7
Molar mass 252.063 g·mol−1
Appearance Orange-red crystals
Odor odorless
Density 2.150 g/cm3 (20 °C (68 °F; 293 K))
Melting point 170 °C (338 °F; 443 K) decomposes
  • 18.2 g/100ml (0 °C (32 °F; 273 K))
  • 35.6 g/100ml (20 °C (68 °F; 293 K))
  • 40.0 g/100ml (25 °C (77 °F; 298 K))
  • 156.0 g/100ml (100 °C (212 °F; 373 K))
Solubility in ethanol soluble
Structure
monoclinic
Hazards
GHS labelling:
Danger
H272, H301, H312, H314, H317, H330, H334, H340, H350, H360, H372, H410
P201, P202, P210, P220, P221, P260, P264, P270, P271, P272, P273, P280, P284, P301+P310+P330, P301+P330+P331, P303+P361+P353, P304+P340+P310, P305+P351+P338+P310, P308+P313, P333+P313, P342+P311, P363, P370+P378, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
218 °C (424 °F; 491 K)
0.0002 mg/m3 (as Cr(VI)) (TWA), 0.0005 mg/m3 (as Cr(VI)) (STEL), 1 mg/10m3 (as CrO3) (C)
Lethal dose or concentration (LD, LC):
  • 53 mg/kg (Rat, oral)
  • 1860 mg/kg (Rabbit, dermal)
0.2 mg/L (200 mg/m3) - 4h (Rat, inhalation, dust / mist)
NIOSH (US health exposure limits):
PEL (Permissible)
0.005 mg/m3 (as Cr)
REL (Recommended)
8 hours, 0.0002 mg/m3 (as Cr)
IDLH (Immediate danger)
15 mg/m3 (as Cr(VI))
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Ammonium dichromate is an inorganic compound with the formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting of ammonium ions and dichromate ions.

Ammonium dichromate is used in demonstrations of tabletop "volcanoes". However, this demonstration has become unpopular due to concerns about the compound's carcinogenic nature. It has been used in pyrotechnics and in the early days of photography. It is also used in holography.