2-Hydroxyethyl methyl terephthalate

2-Hydroxyethyl methyl terephthalate
Names
Other names
  • 1,4-Benzenedicarboxylic acid, 2-hydroxyethyl methyl ester
  • mono(methyl terephthalate)ethylene glycol
  • terephthalic acid, 2-hydroxyethyl methyl ester
  • 1-(2-hydroxyethyl) 4-methyl benzene-1,4-dicarboxylate
  • methyl 2-hydroxyethyl terephthalate
  • monoglycol monomethyl terephthalate
  • β-Hydroxyethyl methyl terephthalate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 222-877-0
UNII
  • InChI=1S/C11H12O5/c1-15-10(13)8-2-4-9(5-3-8)11(14)16-7-6-12/h2-5,12H,6-7H2,1H3
    Key: DJQMYWWZWUOCBQ-UHFFFAOYSA-N
  • COC(=O)C1=CC=C(C=C1)C(=O)OCCO
Properties
C11H12O5
Molar mass 224.212 g·mol−1
Appearance white solid
Melting point 71 °C (160 °F; 344 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

2-Hydroxyethyl methyl terephthalate is an organic compound with the formula HOCH2CH2O2CC6H4CO2CH3. It is a mixed ester of terephthalic acid. This compound is an intermediate in the industrial production of polyethylene terephthalate (>80 Mtons/y) by the transesterification from dimethylterephthalate:

CH3O2CC6H4CO2CH3 + HOCH2CH2OH → HOCH2CH2O2CC6H4CO2CH3 + CH3OH
n HOCH2CH2O2CC6H4CO2CH3 → (OCH2CH2O2CC6H4CO)n + n CH3OH

The compound is also formed by the reverse of the above reaction, the methanolysis of PET.